Metallic, Ceramic and Polymeric Biomaterials. C. Rey, ... D. Grossin, in Comprehensive Biomaterials, 2011 1.111.7.3 CaSO 4-Based Bioactive Ceramics. Calcium sulfate hemihydrate (CaSO 4 ⋅ 1/2H 2 O), known as plaster of Paris, has been used as a building material for at least 5000 years and used by Egyptians to decorate burial tombs of …
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WhatsApp: +86 18221755073α-hemihydrate (α-HH), known for its exceptional mechanical properties, is a widely used building material. Despite its advantages, the traditional method of producing α-HH through regular pressure brine poses significant drawbacks. These include substantial industrial salt demands, high production costs, and water pollution. A more environmentally friendly α …
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WhatsApp: +86 18221755073When gypsum is heated at about 150–160 °C, it loses approximately three-quarters of its water in a partial dehydration process and becomes hemihydrate gypsum (CaSO 4 •½H 2 O) or calcined gypsum; it is also known as beta gypsum (alpha gypsum is made by processing batches of gypsum under elevated pressure). Calcined gypsum or …
WhatsApp: +86 18221755073consumption of hemihydrate and formation of dihydrate. 1. Ultrasonic results indicate gypsum hydration reaction consists of two stages: the dissolution of hemihydrate in the first stage and the nucleation and precipitation of dihydrate in the second stage. 2. Gypsum hydration is strongly influenced by water amount. Spread flow test is
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WhatsApp: +86 18221755073These processes include hemihydrate-dihydrate (HDH), hemihydrate dihydrate recrystallization (HRC), and dihemihydrate (DH/HH) routes (Gobbitt, 2012; Koopman and Witkamp, 2000;Wang et al ...
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WhatsApp: +86 18221755073Analytical grade calcium hydroxide comprised of 96% Ca(OH) 2 and supplied by Tianjin Zhiyuan Chemical Reagent Co. Ltd was used to regulate the pH of hemihydrate phosphogypsum. 2.2. Physical and mechanical properties testing. Water requirement for standard consistency: A total of 300 g hemihydrate phosphogypsum …
WhatsApp: +86 18221755073Author links open overlay panel John M. Gobbitt. Show more. ... Fe 2 O 3 and MgO between the ex-filter acid and the hemihydrate gypsum is expected to be as follows:- Table 6 â€" Approximate distribution of Al 2 O 3, Fe 2 O 3 and MgO % in Filter Acid % in HH Gypsum Al 2 O 3 15 85 Fe 2 O 3 90 10 MgO 95 5 References [1] K.P. Wardle and K ...
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WhatsApp: +86 182217550731. Introduction. Flue gas desulphurization gypsum (FGD gypsum) is an industrial byproduct generated during the desulphurization and purification processes of power plant flue gas emissions [1].This byproduct is primarily comprised of calcium sulfate dihydrate (CaSO 4 ·2H 2 O, DH), along with minor impurities and a high moisture …
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WhatsApp: +86 182217550731. Introduction. Gypsum, an important mineral resource, is widely used in the chemical industry [1], agriculture [2], medical treatment [3], building materials [4], food [5], and other fields, which mainly come from natural and industrial by-products.In the field of chemical industry, gypsum is commonly used as a raw material for the production of …
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WhatsApp: +86 18221755073Median hemidihydrate process requirements are given in Table 2. Dihydrate-Hemihydrate Process (DHH) Although the attack and digestion sections are run under dihydrate conditions, it is not desirable to effect a very high degree of P 2 O 5 recovery during the separation of the acid from the dihydrate because the succeeding dehydration …
WhatsApp: +86 18221755073The process of converting gypsum into alpha hemihydrate involves heating gypsum at a specific temperature to remove water molecules, resulting in a more concentrated and stable form of calcium sulfate. The term "alpha" in alpha hemihydrate refers to the unique crystal structure formed during this dehydration process. The alpha …
WhatsApp: +86 18221755073Direct production of high-strength α-calcium sulfate hemihydrate (α-HH) with no additives was accomplished by the reaction of aluminum sulfate and waste CaCl 2 discarded from Solvay soda plant. For scaling-up this new process, the crystallization kinetics of α-HH was experimentally investigated under varying conditions including …
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WhatsApp: +86 18221755073They observed t 180 of 52 min and 48.2 min with pure FGD and commercial gypsum panels, respectively, without any significant leaching potential. Leiva et al., prepared panels from thermal power plant by-products (FGDG and FA) for the protection of metal structures against fire [94]. Fire resistance of these panels increases with an …
WhatsApp: +86 18221755073This study combined inorganic α-hemihydrate gypsum (α-HHG) with organic polyacrylamide (PAM) hydrogel to create a novel α-HHG/PAM composite material. Through this facile composite strategy, this fabricated material exhibited a significantly longer initial setting time and higher mechanical strength compared to α-HHG. The …
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WhatsApp: +86 18221755073Gypsum (calcium sulfate dihydrate) is one of the most used inorganic binding materials in the world. During calcination, calcium sulfate subhydrates are formed and, for technical reasons, are mixed with water to form dihydrate again. Therefore, the dehydration process of gypsum and the rehydration of hemihydrate were investigated. This …
WhatsApp: +86 18221755073Here we report a facile and cost-effective wet-chemical approach to the synthesis of calcium sulfate hemihydrate nanowires (HH NWs, CaSO4·0.5H2O), and their robust performance in immobilizing …
WhatsApp: +86 18221755073hemihydrate gypsum, and the influence degree of different forms of soluble phosphorus is unclear. Therefore, the utilization of a-hemihydrate gypsum is greatly limited. In this study, the effect of soluble phosphorus on the setting time and mechanical properties of a-hemihydrate gypsum was investi-gated by adding different amounts of H 3PO 4 ...
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